About: Deoxygenation of 5-O-benzoyl-1,2-isopropylidene-3-O-imidazolylthiocarbonyl-α-d-xylofuranose using dimethyl phosphite: an efficient alternate method towards a 3′-deoxynucleoside glycosyl donor

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About: Deoxygenation of 5-O-benzoyl-1,2-isopropylidene-3-O-imidazolylthiocarbonyl-α-d-xylofuranose using dimethyl phosphite: an efficient alternate method towards a 3′-deoxynucleoside glycosyl donor Goto Sponge NotDistinct Permalink

An Entity of Type : schema:ScholarlyArticle, within Data Space : wasabi.inria.fr associated with source document(s)

Attributes	Values
type	Academic Article research paper schema:ScholarlyArticle
isDefinedBy	Covid-on-the-Web dataset
title	Deoxygenation of 5-O-benzoyl-1,2-isopropylidene-3-O-imidazolylthiocarbonyl-α-d-xylofuranose using dimethyl phosphite: an efficient alternate method towards a 3′-deoxynucleoside glycosyl donor
Creator	Vasseur, Jean-Jacques Morvan, François Zlatev, Ivan
source	Elsevier; Medline; PMC
abstract	An efficient radical deoxygenation reaction of thiocarbonylimidazolyl activated glycoside analogue using dimethyl phosphite as hydrogen source and radical chain carrier was performed as a key step in a multi step synthesis towards a common 3-deoxy glycosyl donor for 3′-deoxynucleosides. This method has safety and cost advantages compared to the generally used radical reduction reagents.
has issue date	2008-05-12(xsd:dateTime)
bibo:doi	10.1016/j.tetlet.2008.03.079
bibo:pmid	32287438
has license	no-cc
schema:url	https://doi.org/10.1016/j.tetlet.2008.03.079
resource representing a document's title	Deoxygenation of 5-O-benzoyl-1,2-isopropylidene-3-O-imidazolylthiocarbonyl-α-d-xylofuranose using dimethyl phosphite: an efficient alternate method towards a 3′-deoxynucleoside glycosyl donor
has PubMed Central identifier	PMC7111737
has PubMed identifier	32287438
schema:publication	Tetrahedron Lett
resource representing a document's body	covid:PMC7111737#body_text
is schema:about of	named entity 'phosphite' named entity 'Deoxygenation' named entity 'deoxygenation' named entity 'diol' named entity 'hydroxyl' named entity 'xanthates' named entity 'acid-catalyzed' named entity 'deoxygenation' named entity 'α,β' named entity 'hypophosphorous acid' named entity 'deprotection' named entity 'deoxy' named entity 'deoxy' named entity 'dimethyl phosphite' named entity 'nucleoside' named entity 'hydroxyl groups' named entity 'deoxygenation' named entity '1.2' named entity 'glycoside' named entity 'free radical' named entity 'deoxy sugar' named entity 'deoxygenation' named entity 'acetyl' named entity 'glycoside' named entity 'chromatography' named entity 'deoxygenation' named entity 'd-glucose' named entity 'd-glucose' named entity 'deoxynucleosides' named entity 'nucleosides' named entity 'xanthates' named entity 'glycoside' named entity 'hydroxyl' named entity 'silanes' named entity 'vacuum' named entity 'chemical modification' named entity 'nucleoside' named entity 'dimethyl phosphite' named entity 'ammonia' named entity 'thiocarbonyldiimidazole' named entity 'non-toxic' named entity 'nucleoside' named entity 'hydrogen' named entity 'acetone' named entity 'acetal' named entity 'deoxyribofuranose' named entity 'silica gel' named entity 'hydroxy group' named entity 'radical chain' named entity 'glycosyl donor' named entity 'hydroxyl' named entity 'reagent' named entity 'SARS' named entity 'benzoylated' named entity 'reaction yield' named entity 'reaction yields' named entity 'dimethyl phosphite' named entity 'evaporation' named entity 'nucleoside analogues' named entity 'acetylation' named entity 'd-glucose' named entity 'furanose' named entity 'antiviral' named entity 'dimethyl phosphite' named entity 'oligoribonucleotides' named entity 'glycosyl' named entity 'tributyltin hydride' named entity 'moiety' named entity 'benzoyl peroxide' named entity 'hydrolysis' named entity 'glycosylation' named entity 'dimethyl phosphite' named entity 'chromatography' named entity 'deoxynucleosides' named entity 'hydrolysis' named entity 'hydrogen' named entity 'free radical' named entity 'hydride' named entity 'triethylsilane' named entity 'radical chain'

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