About: Highly Catalytic Enantioselective Reformatsky Reaction with Aldehydes and Ketones Using an Available Prolinol Ligand

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About: Highly Catalytic Enantioselective Reformatsky Reaction with Aldehydes and Ketones Using an Available Prolinol Ligand Goto Sponge NotDistinct Permalink

An Entity of Type : schema:ScholarlyArticle, within Data Space : wasabi.inria.fr associated with source document(s)

Attributes	Values
type	Academic Article research paper schema:ScholarlyArticle
isDefinedBy	Covid-on-the-Web dataset
title	Highly Catalytic Enantioselective Reformatsky Reaction with Aldehydes and Ketones Using an Available Prolinol Ligand
Creator	Liao, Jianhua Luo, Renshi Ouyang, Lu Wei, Yifei Xia, Yanping
source	Medline; PMC
abstract	[Image: see text] A highly Me(2)Zn-mediated catalytic enantioselective Reformatsky reaction of aldehydes and ketones with ethyl iodoacetate using a readily available prolinol ligand is reported. This reaction provides an efficient method for the construction of β-hydroxy esters in up to 98% yield and 95% enantiomeric excess (ee) value. A wide range of functional groups are tolerated and the practicality of this protocol is demonstrated by performing the reaction on a gram scale.
has issue date	2020-06-26(xsd:dateTime)
bibo:doi	10.1021/acsomega.0c02400
bibo:pmid	32685867
has license	no-cc
sha1sum (hex)	fc2f432c8126a8b1e400f8d9d6c0a594a48f07a4
schema:url	https://doi.org/10.1021/acsomega.0c02400
resource representing a document's title	Highly Catalytic Enantioselective Reformatsky Reaction with Aldehydes and Ketones Using an Available Prolinol Ligand
has PubMed Central identifier	PMC7366354
has PubMed identifier	32685867
schema:publication	ACS Omega
resource representing a document's body	covid:fc2f432c8126a8b1e400f8d9d6c0a594a48f07a4#body_text
is schema:about of	named entity 'wide range' named entity 'Ketones' named entity 'KETONES' named entity 'UP TO' named entity 'GRAM' covid:arg/fc2f432c8126a8b1e400f8d9d6c0a594a48f07a4 named entity 'Reformatsky reaction' named entity 'enantioselective' named entity 'prolinol' named entity 'ligand' named entity '95%' named entity 'ethyl iodoacetate' named entity 'Aldehydes' named entity 'Ligand' named entity 'efficient' named entity 'HPLC' named entity 'aldehydes' named entity 'ethyl iodoacetate' named entity 'aqueous solution' named entity 'ligands' named entity 'column chromatograph' named entity 'carbonyl compounds' named entity 'solvent' named entity 'Aldehydes' named entity 'mmol' named entity 'toluene' named entity 'ligand' named entity '1.2' named entity 'propanoate' named entity '1.2' named entity 'enantioselective' named entity 'enantiomeric excess' named entity 'electron-donating' named entity 'm/z' named entity 'm/z' named entity 'Reformatsky reaction' named entity 'Ph 3' named entity 'toluene' named entity 'electron-withdrawing' named entity '220 nm' named entity 'ketones' named entity 'enantioselectivity' named entity 'vacuum' named entity 'HPLC' named entity 'mass spectrometry' named entity 'Daicel' named entity 'Reformatsky reaction' named entity 'ketones' named entity 'Reformatsky reaction' named entity 'enantioselectivities' named entity 'Daicel' named entity 'chiral' named entity 'petroleum ether' named entity '7.2' named entity 'ligand' named entity 'Reformatsky reaction' named entity '14.1' named entity 'Chemical shifts' named entity 'Daicel' named entity 'enantiomeric excess' named entity 'i-PrOH' named entity 'Reformatsky reaction' named entity 'Ethyl' named entity 'Reformatsky reaction' named entity 'MgSO' named entity 'ethyl iodoacetate' named entity 'esters' named entity 'functional groups' named entity 'prolinol' named entity 'ortho' named entity 'electron' named entity 'ultraviolet light' named entity 'enantioselectivities' named entity 'dichloromethane' named entity 'aldehydes' named entity 'Schiff base' named entity 'CDCl'

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